Simple manganese carbonyl catalyzed hydrogenation of quinolines and imines |
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| Affiliation: | 1. Institut des Sciences Chimiques de Rennes, UMR 6226 CNRS Université de Rennes 1, Team Organometallics: Materials and Catalysis, 263 avenue du Général Leclerc, 35046 Rennes Cedex, France;2. Institut Universitaire de France, 1 rue Descartes, 75231 Paris Cedex 05, France;1. LCC-CNRS, Université de Toulouse, CNRS, UPS, Toulouse, France;2. Univ Rennes, CNRS, ISCR – UMR 6226, F-35000 Rennes, France;3. Institut Universitaire de France, 1 rue Descartes, 75231 Paris Cedex 05, France |
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| Abstract: | Manganese-catalyzed hydrogenation of unsaturated molecules has made tremendous progresses recently benefiting from non-innocent pincer or bidentate ligands for manganese. Herein, we describe the hydrogenation of quinolines and imines catalyzed by simple manganese carbonyls, Mn2(CO)10 or MnBr(CO)5, thus eliminating the prerequisite pincer-type or bidentate ligands. |
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| Keywords: | Manganese Hydrogenation Quinolines Imines Homogeneous catalysis |
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