Recent advances for the photoinduced CC bond cleavage of cycloketone oximes |
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| Institution: | 1. School of Pharmaceutical and Materials Engineering & Institute for Advanced Studies, Taizhou University, Taizhou 318000, China;2. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China;1. School of Pharmaceutical and Materials Engineering & Institute for Advanced Studies, Taizhou University, Taizhou 318000, China;2. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China;1. Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock, Germany;2. Univ Rennes, CNRS, ISCR UMR 6226, F-35000 Rennes, France |
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| Abstract: | Nitriles are widely existed in many bioactive compounds, and they can be easily transformed into other functional groups. Therefore, the synthesis of nitriles under cyanide-free conditions is of significant importance. Recent advances for the synthesis of nitriles through photoinduced C C bond cleavage of cycloketone oximes classified by the type of CX bond forming are summarized. Various compounds possessing nitriles can be efficiently accessed via this method. |
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| Keywords: | Nitriles Cycloketone oximes Radical Photocatalysis |
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