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Fluorescence-resonance energy transfer (FRET) within the fluorescent metallacycles
Affiliation:1. College of Chemistry and Chemical Engineering, State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, PR China;2. Quality and Technical Supervision and Inspection of Jin Chang, Jinchang 737100, PR China;1. Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China;2. State Key Laboratory of Precision Spectroscopy, East China Normal University, Shanghai 200241, China;3. Zhejiang Provincial Key Laboratory of Chemical Utilization of Forestry Biomass, Department of Chemistry, Zhejiang A&F University, Hangzhou 311300, China;4. College of Chemistry, Beijing Normal University, Beijing 100050, China;1. College of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China;2. College of Computer Science, Nankai University, Tianjin 300350, China;3. College of Sciences, Henan Agricultural University, Zhengzhou 450001, China
Abstract:During past few years, the construction of fluorescent metallacycles featuring the fluorescence-resonance energy transfer behavior has attracted extensive attention due to their diverse applications such as real-time monitoring the dynamics of coordination-driven self-assembly, photoswitching fluorescence-resonance energy transfer, and light-controlled generation of singlet oxygen for cancer therapy. This review focuses on the recent advances on the design principles, preparation methods, optical properties, and the wide applications of fluorescent metallacycles with the FRET property.
Keywords:Fluorescence-resonance energy transfer  Coordination-driven self-assembly  Metallacycle  Fluorescent material  Supramolecular chemistry
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