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AgGaS2晶体生长成核研究
引用本文:李一春,赵北君,朱世富,王瑞林,张伟,刘敏文,刘娟,陈宝军,张建军. AgGaS2晶体生长成核研究[J]. 人工晶体学报, 2004, 33(2): 231-234
作者姓名:李一春  赵北君  朱世富  王瑞林  张伟  刘敏文  刘娟  陈宝军  张建军
作者单位:四川大学材料科学系,成都,610064
摘    要:本文在对红外非线性光学材料AgGaS2的DTA谱线进行分析的基础上,对AgGaS2的结晶习性进行了研究.对传统的Bridgman-Stockbarger法进行了改进,设计出新的三温区立式炉,炉内温度梯度达到生长晶体的要求.根据自发成核的几何淘汰理论,针对AgGaS2的结晶特点,设计出适宜的石英生长安瓿,形状能够满足AgGaS2晶体结晶习性的需要,成功地生长出完整性较好的尺寸达10mm×25mm的AgGaS2单晶体.

关 键 词:红外非线性光学材料  硫镓银  晶体生长  温度梯度  安瓿设计,
文章编号:1000-985X(2004)02-0231-04

Nucleation Studies of AgGaS2 Single Crystal
LI Yi-chun,ZHAO Bei-jun,ZHU Shi-fu,WANG Rui-lin,ZHANG Wei,LIU Min-wen,LIU Juan,CHEN Bao-jun,ZHANG Jian-jun. Nucleation Studies of AgGaS2 Single Crystal[J]. Journal of Synthetic Crystals, 2004, 33(2): 231-234
Authors:LI Yi-chun  ZHAO Bei-jun  ZHU Shi-fu  WANG Rui-lin  ZHANG Wei  LIU Min-wen  LIU Juan  CHEN Bao-jun  ZHANG Jian-jun
Abstract:This paper reported the studies of crystalline characters of the nonlinear optical material AgGaS_2 according to the analysis of the measured DTA curve.The traditional Bridgman-Stockbarger method was improved, a new design of furnace that has three temperature-zone was performed, and the temperature gradient fit to well the need of AgGaS_2 crystal growth. The appropriate quartz growth ampoule was designed on the basis of the geometry eliminate theory about nucleation. Integral AgGaS_2 single crystal with the diameter of 10mm and the length of 25mm was obtained successfully under these conditions.
Keywords:IR nonlinear optical material  AgGaS_2  crystal growth  temperature gradient  ampoule design
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