Synthesis and structures of M[N(TePPri2)2-Te,Te']n (n = 2, M = Zn, Cd, Hg; n = 3, M = Sb, Bi): the first ditelluroimidodiphosphinato p- and d-block metal complexes |
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| Authors: | Chivers Tristram Eisler Dana J Ritch Jamie S |
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| Institution: | Department of Chemistry, University of Calgary, Calgary, AB, Canada T2N 1N4. chivers@ucalgary.ca |
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| Abstract: | Reactions of NaN(TePPri2)2] with the appropriate metal halide produce the air-stable complexes MN(TePPri2)2-Te,Te']n (n = 2, M = Zn, Cd, Hg; n = 3, M = Sb, Bi), which adopt distorted tetrahedral (M = Zn, Cd, Hg) and octahedral (M = Sb, Bi) structures, respectively. |
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