MLCT excited states in Ru(II) complexes: Reactivity and related two-photon absorption applications in the near-infrared spectral range |
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| Authors: | Gilles Lemercier, Adeline Bonne, Mickaë l Four,Lat vi M. Lawson-Daku |
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| Affiliation: | aUniversité de Lyon, laboratoire de chimie, École normale supérieure de Lyon, CNRS, France, 46, allée d'Italie, F-69364 Lyon cedex 07, France;bFacultés des sciences – Université de Genève, 30 quai Ernest-Ansermet, CH-1211 Genève 4, Switzerland |
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| Abstract: | This short review provides a concise summary of the current state of research on the population by two-photon absorption of the triplet metal-to-ligand 3MLCT excited state of ruthenium(II) complexes. Several effective and potential applications of this nonlinear optics phenomenon (optical power limiting in the near infrared, biological imagery and photodynamic therapy, PDT) and related linear effects will also be presented. |
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| Keywords: | Ruthenium(II) complexes Polypyridyl ligands Two-photon absorption 3MLCT Dioxygen sensors Photodynamic therapyMots-clé s: Complexes du ruthenium(II) Ligand polypyridyle 3MLCT Absorption à deux photons Dosage du dioxygè ne Thé rapie photodynamique |
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