Aminomethylphosphines in template synthesis on Pt(II), Pd(II), and Hg(II) |
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| Authors: | G. N. Nikonov A. A. Karasik E. V. Malova K. M. Enikeev |
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| Affiliation: | A. E. Arbuzov Institute of Organic and Physical Chemistry, Academy of Sciences of the USSR, Kazan Branch, Kazan, USSR |
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| Abstract: | Reactions of 5-p-toluidinomethyl-1,3-ditolyl-1,3,5-diazaphosphorinane 1 with Pt(II), Pd(II), Hg(II) salts are reported. Complex formation was followed by template synthesis of novel bicyclic ligand and chelate complexes. Compounds 2 , 3 , 4 have been formed. The mercury complex 4 was also obtained in high yield by electrochemical oxidation of compound 1 at the Hg-anode. Conformational features of new ligands are discussed on the basis of NMR data. |
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