Lithiosilanes and their application to the synthesis of polysilane dendrimers |
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Authors: | Akira Sekiguchi Vladimir Ya. Lee Masato Nanjo |
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Affiliation: | Department of Chemistry, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan |
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Abstract: | An account is given of the preparation and structural investigations of silyllithium compounds, including X-ray and NMR data. This review covers the chemistry of lithiosilanes with alkyl, aryl, functional substituents and lithiooligosilanes with Si---Si bonds. Application of lithiosilanes for the synthesis of polysilane dendritic molecules is also described. |
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Keywords: | Silicon derivatives Silyllithium compounds Group I metals Dendrimer Polysilane |
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