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Lithiosilanes and their application to the synthesis of polysilane dendrimers
Authors:Akira Sekiguchi   Vladimir Ya. Lee  Masato Nanjo
Affiliation:

Department of Chemistry, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan

Abstract:An account is given of the preparation and structural investigations of silyllithium compounds, including X-ray and NMR data. This review covers the chemistry of lithiosilanes with alkyl, aryl, functional substituents and lithiooligosilanes with Si---Si bonds. Application of lithiosilanes for the synthesis of polysilane dendritic molecules is also described.
Keywords:Silicon derivatives   Silyllithium compounds   Group I metals   Dendrimer   Polysilane
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