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A Novel Octahedral Hexasilver(I) Cluster: Ag_6[SSCN(n-C_4H_9)_2]_6
引用本文:章伟光,钟昀,谭民裕,刘伟生,苏成勇. A Novel Octahedral Hexasilver(I) Cluster: Ag_6[SSCN(n-C_4H_9)_2]_6[J]. 中国化学, 2002, 0(5)
作者姓名:章伟光  钟昀  谭民裕  刘伟生  苏成勇
作者单位:ZHANG,Wei Guang ZHONG,Yun TAN,Min YuLIU,Wei Sheng SU,Cheng Yong aDepartment of Chemistry,Lanzhou University,Lanzhou,Gansu 730000,China bDepartment of Chemistry,South China Normal University,Guangzhou,Guangdong 510631,Ch
基金项目:ProjectsupportedbytheNaturalScienceFoundationofGuangdongProvince (No .990 4 63)andtheNationalNaturalScienceFounda tionofChina (No .2 95 6 10 0 2 )
摘    要:CompoundsformedfromCu ,AgandAuwithdithio lateligands ,suchasthedialkyldithiocarbamate (DTC) ,mercaptothiazoline (HMT)anddialkyldithiophosphates(DDP) ,haveplayedanimportantroleintechnology .1Cu(I) Sclustersalsohavebeenimplicatedinbiologyasan ti oxidants .2Thecuban…


A Novel Octahedral Hexasilver(I) Cluster: Ag_6[SSCN(n-C_4H_9)_2]_6
ZHANG,Wei Guang ZHONG,Yun TAN,Min YuLIU,Wei Sheng SU,Cheng Yong a. A Novel Octahedral Hexasilver(I) Cluster: Ag_6[SSCN(n-C_4H_9)_2]_6[J]. Chinese Journal of Chemistry, 2002, 0(5)
Authors:ZHANG  Wei Guang ZHONG  Yun TAN  Min YuLIU  Wei Sheng SU  Cheng Yong a
Affiliation:ZHANG,Wei Guang ZHONG,Yun TAN,Min YuLIU,Wei Sheng SU,Cheng Yong aDepartment of Chemistry,Lanzhou University,Lanzhou,Gansu 730000,China bDepartment of Chemistry,South China Normal University,Guangzhou,Guangdong 510631,Ch
Abstract:The first crystal structural report of a AgDTC complex (DTC= dialkyldithiocarbamate, R= n butyl) presented in this paper shows that it is a hexanuclear species. The structural arrangement for the DDP (dialkyldithiophosphate) ligands is different from that of Cu 6(DDP) 6, but is the same as that of Ag 6 [SSP(O i Pr) 2] 6.
Keywords:X ray crystal structure   cluster   silver n dibutyldithiocarbamate complex
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