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Low-frequency Raman scattering in superionic Li2SO4
Affiliation:1. Department of Chemical and Geological Sciences, Al-Hikmah University, Ilorin PMB1601, Nigeria;2. Department of Industrial Chemistry, University of Ilorin, PMB 1515 Ilorin, Nigeria;3. Department of Chemistry, Federal University of Technology, Bosso Campus, Minna PMB 65, Nigeria;4. Nanotechnology Research Group, African Centre of Excellence on Food Safety and Mycotoxins, Federal University of Technology, P.M.B 65, Bosso, Minna, Niger State, Nigeria;1. Clean Energy Research Center, Korea Institute of Science and Technology, 5 Hwarang-ro 14-gil, Seongbuk-gu, Seoul, Republic of Korea;2. Division of Energy and Environment Technology, KIST School, University of Science and Technology (UST), 217 Gajeong-ro, Yuseong-gu, Daejeon, Republic of Korea
Abstract:The low-frequency Raman spectra of fcc Li2SO4 are found to contain a broad and a narrow component centered at zero frequency. The narrow component is identified with the relaxation mode due to the time of flight of Li+.
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