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Catalytic ammonia reforming: alternative routes to net-zero-carbon hydrogen and fuel
Authors:Luis C. Caballero  Nicholas E. Thornburg  Michael M. Nigra
Affiliation:Department of Chemical Engineering, University of Utah, Salt Lake City UT USA.; Center for Integrated Mobility Sciences, National Renewable Energy Laboratory, Golden CO USA,
Abstract:Ammonia is an energy-dense liquid hydrogen carrier and fuel whose accessible dissociation chemistries offer promising alternatives to hydrogen electrolysis, compression and dispensing at scale. Catalytic ammonia reforming has thus emerged as an area of renewed focus within the ammonia and hydrogen energy research & development communities. However, a majority of studies emphasize the discovery of new catalytic materials and their evaluation under idealized laboratory conditions. This Perspective highlights recent advances in ammonia reforming catalysts and their demonstrations in realistic application scenarios. Key knowledge gaps and technical needs for real reformer devices are emphasized and presented alongside enabling catalyst and reaction engineering fundamentals to spur future investigations into catalytic ammonia reforming.

Ammonia is a promising net-zero-carbon energy vector whose hydrogen content is accessible via multiple catalytic pathways. This perspective highlights advances in NH3 reforming catalysis and opportunities for reaction engineering of reformer devices.
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