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Magnetic properties of lithium intercalation compounds
Authors:C M Julien  A Ait-Salah  A Mauger  F Gendron
Institution:(1) Institut des Nano-Sciences de Paris (INSP), Université Pierre et Marie Curie, CNRS-UMR 7588, Campus Boucicaut, 140 rue de Lourmel, 75015 Paris, France;(2) Department MIPPU, CNRS, Campus Boucicaut, 140 rue de Lourmel, 75015 Paris, France
Abstract:Magnetic experiments are powerful tools to study fundamental properties and to check the qualities of samples. Temperature, stress, and impurities of materials can all affect magnetic properties and play an important role in the utilization of these materials for engineering applications. The estimation and analysis of the spontaneous magnetization can reveal ferromagnetic particles as impurities in samples. The shape of the temperature dependence of magnetization is indicative of the origin of the magnetic properties. However, it is necessary to correlate the χ m (T) curves and isothermal M(H) plots to achieve a complete analysis of the electronic properties of the materials. Highlights of magnetic properties of lithium intercalation compounds are briefly described. Intrinsic and extrinsic properties are considered as useful parameters to determine the purity of electrode materials for rechargeable Li-ion batteries.
Keywords:Li-ion batteries  Intercalation compounds  Magnetic properties  Clustering
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