| 时域反射光谱法研究酰胺-醇混合物的介电驰豫 |
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| 引用本文： | RAMACHANDRAN K.,SIVAGURUNATHAN P.,DHARMALINGAM K.,MEHROTRA S. C..时域反射光谱法研究酰胺-醇混合物的介电驰豫[J].物理化学学报,2007,23(10):1508-1514. |
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| 作者姓名： | RAMACHANDRAN K. SIVAGURUNATHAN P. DHARMALINGAM K. MEHROTRA S. C. |
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| 作者单位： | Department of Physics, SRMUniversity, Kattankulathur-603 203, Tamilnadu, India; Department of Physics, Annamalai University, Annamalai Nagar-608 002, Tamilnadu, India; Department of Electronics and Computer Science,;
Dr. B. A. M. University, Aurangabad-431 004, Maharashtra, India |
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| 摘 要： | Using time domain reflectometry （TDR）, dielectric relaxation studies were carded out on binary mixtures of amides （N-methylformamide （NMF） and N,N-dimethylformamide （DMF）） with alcohols （1-butanol, 1-pentanol, 1- hexanol, 1-heptanol, 1-octanol, and 1-decanol） for various concentrations over the frequency range from 10 MHz to 10 GHz at 303 K. The Kirkwood correlation factor and excess dielectric constant properties were determined and discussed to yield information on the molecular interactions of the systems. The relaxation time varied with the chain length of alcohols and substituted amides were noticed. The Bruggeman plot shows a deviation from linearity. This deviation was attributed to some sort of molecular interaction which may take place between the alcohols and substituted amides. The excess static permittivity and excess inverse relaxation time values varied from negative to positive for all the systems indicating that the solute-solvent interaction existed between alcohols and substituted amides for all the dynamics of the mixture.
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| 关 键 词： | 介电松弛 时域反射计 氨基化合物 甲醇 混合试剂 |
| 收稿时间： | 2007-05-07 |
| 修稿时间： | 2007-05-07 |
Dielectric Relaxation Study of Amide-Alcohol Mixtures by Using Time Domain Reflectometry |
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| RAMACHANDRAN K.,SIVAGURUNATHAN P.,DHARMALINGAN K.. MEHROTRA S. C..Dielectric Relaxation Study of Amide-Alcohol Mixtures by Using Time Domain Reflectometry[J].Acta Physico-Chimica Sinica,2007,23(10):1508-1514. |
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| Authors: | RAMACHANDRAN K SIVAGURUNATHAN P DHARMALINGAN K MEHROTRA S C |
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| Institution: | Department of Physics, SRMUniversity, Kattankulathur-603 203, Tamilnadu, India; Department of Physics, Annamalai University, Annamalai Nagar-608 002, Tamilnadu, India; Department of Electronics and Computer Science,;
Dr. B. A. M. University, Aurangabad-431 004, Maharashtra, India |
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| Abstract: | Using time domain reflectometry (TDR), dielectric relaxation studies were carried out on binary mixtures of amides (N-methylformamide (NMF), N,N-dimethylformamide (DMF)) with alcohols (1-butanol, 1-pentanol, 1-hexanol, 1-heptanol, 1-octanol, and 1-decanol) for various concentrations over the frequency range from 10 MHz to 10 GHz at 303 K. The Kirkwood correlation factor and excess dielectric constant properties were determined and discussed to yield information on the molecular interactions of the systems. The relaxation time varied with the chain length of alcohols and substituted amides were noticed. The Bruggeman plot shows a deviation from linearity. This deviation was attributed to some sort of molecular interaction which may take place between the alcohols and substituted amides. The excess static permittivity and excess inverse relaxation time values varied from negative to positive for all the systems indicating that the solute-solvent interaction existed between alcohols and substituted amides for all the dynamics of the mixture. |
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| Keywords: | Dielectric relaxation Time domain reflectometry Bruggeman factor Kirkwood correlationfactor |
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