Bridging ligand planarity as a route to long-lived, near infrared emitting dinuclear ruthenium(II) complexes |
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| Authors: | Polson Matthew I J Loiseau Frédérique Campagna Sebastiano Hanan Garry S |
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| Institution: | Département de Chimie, Université de Montréal, 2900 Edouard-Montpetit, Montréal, Québec H3T-1J4, Canada. |
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| Abstract: | The dinuclear ruthenium complex of a large, planar bis-tridentate bridging ligand has been prepared; to the best of our knowledge, this species is the near IR-emitting Ru(II) complex exhibiting the longest-lived emission and highest quantum yield reported so far, due to the dramatic reduction in its radiationless decay rate constant. |
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