General concept of increasing crystal symmetry with an increase in temperature |
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Authors: | S. K. Filatov |
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Affiliation: | 1.St. Petersburg State University,St. Petersburg,Russia |
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Abstract: | A general concept of the symmetry transformation of a material during its thermal expansion and final polymorphic transition is proposed based on numerous experimental data. Within this concept, the atomic nature of the transformation of the crystal structure with a change in temperature is considered. Particular attention is paid to the thermal expansion of materials, along with the well-known tendency of a thermally induced increase in the crystal symmetry, which is generally considered to be the directionality of material transformation during polymorphic transitions. |
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