Characteristic changes of pH during the alkalization of latex dispersions of the ethyl acrylate — methacrylic acid copolymers |
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Authors: | O. Quadrat L. Mrkvičková E. Jasná J. Šňupárek Jr |
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Affiliation: | (1) Present address: Institute of Macromolecular Chemistry, Czechoslovak Academy of Sciences, Prague, Czechoslovakia;(2) Research Institut for Synthetic Resins and Lacquers Pardubice, Czechoslovakia |
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Abstract: | The titration curves of latex dispersions of ethyl acrylate — methacrylic acid copolymers have a rather complex shape which indicates a strong dependence of the apparent dissociation constant of carboxylic groups on the degree of neutralization and copolymer composition. These dependences seem to be related to changes in the macroscopic structure (swelling and disintegration) of dispersion particles during alkalization. |
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Keywords: | Latexdispersions copolymers ofethylacrylate withmethacrylicacid titrationcurves |
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