| 四中位（邻烷基）苯基卟啉及其高铁络合物的合成及光谱性质 |
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| 引用本文： | 桂明德,蒋笃孝.四中位（邻烷基）苯基卟啉及其高铁络合物的合成及光谱性质[J].高等学校化学学报,1994,15(10):1489-1493. |
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| 作者姓名： | 桂明德 蒋笃孝 |
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| 作者单位： | 天津南开大学化学系，暨南大学化学系 |
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| 基金项目： | 国家自然科学基金,国家教委博士点基金 |
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| 摘 要： | 合成了６种不同大小的烷基取代的四中位（邻烷基）苯基卟啉Ｔ＿（Ｏ－Ｒ）ＰＰＨ＿２及其高铁络合物Ｔ＿（Ｏ－Ｒ）ＰＰＦｅＣｌ（Ｒ＝ＣＨ＿３，Ｃ＿２Ｈ＿５，ｎ－Ｃ＿３Ｈ＿７，ｉ－Ｃ＿３Ｈ＿７，ｎ－Ｂｕ，ｔ－Ｂｕ），除Ｒ＝ＣＨ＿３外，其它５种是文献未曾报道过的新化合物。测定了它们的核磁共振谱、红外及电子光谱，并讨论了它们的结构与光谱性质的关系．
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| 关 键 词： | 邻烷基 苯基卟啉 高铁络合物 合成 |
Synthesis and Spectra Determination of 5,10,15,20-Tetrakis-(2-alkylphenyl)porphyrins and Their Ferric Complex Salts |
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| GUI Ming-De,JIANG Du-Xiao,ZHU Shen-Jie.Synthesis and Spectra Determination of 5,10,15,20-Tetrakis-(2-alkylphenyl)porphyrins and Their Ferric Complex Salts[J].Chemical Research In Chinese Universities,1994,15(10):1489-1493. |
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| Authors: | GUI Ming-De JIANG Du-Xiao ZHU Shen-Jie |
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| Abstract: | Six different 5,10,15,20-tetrakis(2-alkylphenyl)porphyrins(T_(O-R)PPH2)and their ferric complex salts T_(O-R)PPFeCl(R=Me,Et,n-Pr,i-Pr,n-Bu,t-Bu)were synthesized.Besides R=Me is known,all others are new compounds.We found that T_(O-i-Pr)PPH2,T_(O-t-Bu)PPH2,and T_(O-i-Pr)PPFeCl, T_(O-t-Bu)PPFeCl were more difficult to formation than other T_(O-R)PPH2 and T_(O-R)TTPFeCl.Their IR and UV-Vis spectra were determined and the relationship between the structures and the spectral properties was discussed. |
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| Keywords: | T_(O-R)PPFeCl Steric effect Synthesis Spectral property |
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