Metal - MoOx interaction and hydrodesulfurization activity of PdMo and PtMo catalysts |
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| Authors: | Pál Tétényi and Victor Galsán |
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| Institution: | (1) Hungarian Academy of Sciences, Institute of Isotope and Surface Chemistry, Chemical Research Center, H-1525 Budapest, P.O.Box 77, Hungary |
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| Abstract: | The ratios of the benzene/cyclohexane and of toluene/cyclohexane adsorption equilibrium constants were determined from the dehydrogenation rates of cyclohexane in its binary mixtures with benzene and toluene, respectively. The calculated adsorption constant ratios of toluene/benzene indicate a Pd Mo and a MoPt electron transfer. The opposite direction of the two electron transfers is compared with XPS and catalytic activity data. |
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| Keywords: | toluene PtMo adsorption constants PdMo benzene Cyclohexane |
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