Solvolysis of a tetrahydropyranyl mesylate: mechanistic implications for the Prins cyclization, 2-oxonia-cope rearrangement, and Grob fragmentation |
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| Authors: | Jasti Ramesh Rychnovsky Scott D |
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| Affiliation: | Department of Chemistry, University of California, Irvine, 92697-2025, USA. |
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| Abstract: | [reaction: see text] A solvolysis reaction is used to demonstrate that a tetrahydropyranyl cation is a common intermediate for Prins cyclizations, 2-oxonia-Cope rearrangements, and Grob fragmentations of tetrahydropyran rings. |
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