Influence of substituents on rate constants for recombination of tertiary peroxy radicals |
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| Authors: | S L Khursan and V S Martemyanov |
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| Institution: | (1) State University, 450074 Ufa, USSR |
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| Abstract: | A linear correlation between the logarithm of rate constant (2kt) for recombination of tertiary peroxy radicals (ROO )* and  * constants of substituents R was found to be 1g 2kt=lg 2k
t
°
. The calculated values are 1g 2k
t
°
=4.59±0.08 and  *=5.56±0.35.
                     I (2kt)     (ROO)   R: 1g 2kt=lg 2k
t
°
.  , 1g 1g 2k
t
°
=4,59±0,08 =5,56±0,35
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| Keywords: | |
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