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Potassium Ferrites Formation in Promoted Hematite Catalysts for Dehydrogenation. Thermal and structural analyses
Authors:Surman  J  Majda  D  Rafalska-Łasocha  A  Kuśtrowski  P  Chmielarz  L  Dziembaj  R
Institution:(1) Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060 Cracow, Poland;(2) Regional Laboratory for Physicochemical Analyses and Structural Research, Jagiellonian University, Ingardena 3, 30-060 Cracow, Poland
Abstract:K-promoted hematite catalysts for ethylbenzene dehydrogenation were studied by thermal analysis (TG/DTG) and high-temperature XRD. The formation of potassium ferrite (K2Fe2O4), considered to be a catalytically active phase, was observed during calcination of the Ce-promoted catalysts. A linear correlation of the catalytic activity and the temperature of potassium ferrites formation was found. This revised version was published online in July 2006 with corrections to the Cover Date.
Keywords:DTG  ethylbenzene dehydrogenation  hematite catalysts  potassium ferrites  XRD
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