A (salicylidene)aniline derived Schiff-base adduct of methyltrioxorhenium(VII)-Cis-and trans-coordination of the ligand |
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| Authors: | Ming-Dong Zhou Shu-Liang Zang |
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| Institution: | a Molekulare Katalyse, Fakultät für Chemie der Technischen Universität München, Lichtenbergstrasse 4, D-85747 Garching bei München, Germany
b Department of Petroleum and Chemical Technology, Liaoning University of Petroleum and Chemical Technology, Dandong Road, No. 1, 113001 Fushun, PR China |
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| Abstract: | A (salicylidene)aniline derived Schiff-base adduct of methyltrioxorhenium(VII), displaying both a cis- and a trans-arrangement of the Schiff-base ligand to the Re bound methyl group has been synthesized and described. Despite displaying some significant differences in the solid state (e.g. Re-O (Schiff base) bond distance, Re-C bond distance and several bond angles), the two configurations are indistinguishable in solution, obviously interchanging quickly. |
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| Keywords: | Catalysis Methyltrioxorhenium(VII) Salicylidene(aniline) Schiff base Solid state structure |
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