| 聚乙二醇稳定的RuB纳米粒子催化苯选择加氢为环己烯的性能研究 |
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| 引用本文： | 张晔,付海燕,李瑞祥,陈华,李贤均. 聚乙二醇稳定的RuB纳米粒子催化苯选择加氢为环己烯的性能研究[J]. 无机化学学报, 2013, 29(3): 577-582 |
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| 作者姓名： | 张晔 付海燕 李瑞祥 陈华 李贤均 |
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| 作者单位： | 1. 赤峰学院化学化工学院,赤峰,024000
2. 四川大学化学学院,教育部绿色化学与技术重点实验室,成都610064 |
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| 摘 要： | PEG稳定的RuB纳米粒子对苯选择加氢制备环己烯显示出良好的催化性能,在不添加硫酸锌的条件下,该体系催化的苯选择性加氢中,环己烯收率高达29%。这一体系的高催化性能是由于PEG稳定的RuB纳米粒子,使催化剂表面的亲水性增强,提高了环己烯的选择性。
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| 关 键 词： | Ru 苯 环己烯 加氢。 |
| 收稿时间： | 2012-06-07 |
| 修稿时间： | 2012-07-26 |
Polyethylene Glycol Stabilized RuB Nanoparticles: an Effective Catalyst for Selective Hydrogenation of Benzene to Cyclohexene |
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| ZHANG Ye,FU Hai-Yan,LI Rui-Xiang,CHEN Hua and LI Xian-Jun. Polyethylene Glycol Stabilized RuB Nanoparticles: an Effective Catalyst for Selective Hydrogenation of Benzene to Cyclohexene[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(3): 577-582 |
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| Authors: | ZHANG Ye FU Hai-Yan LI Rui-Xiang CHEN Hua LI Xian-Jun |
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| Affiliation: | College of Chemistry and Chemical Technology, Chifeng University, Chifeng, Inner Mongolia 024000, China;Key Lab of Green Chemistry and Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China;Key Lab of Green Chemistry and Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China;Key Lab of Green Chemistry and Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China;Key Lab of Green Chemistry and Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China |
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| Abstract: | The Polyethylene Glycol(PEG)stabilized RuB nanoparticles showed an excellent catalytic performance for selective hydrogenation of benzene to cyclohexene. Without ZnSO4, a maximum cyclohexene yield of 29% was obtained. The good performance of this catalyst system is attributed to the great hydrophilic property of RuB nanoparticles caused by PEG. |
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| Keywords: | ruthenium benzene cyclohexene hydrogenation |
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