The first A2B2-heterometal ferrimagnetic chain. Structures and magnetic properties of polymeric [Gd2Cu2]n and the corresponding monomer |
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| Authors: | Ueki Sohei Kobayashi Yasuko Ishida Takayuki Nogami Takashi |
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| Affiliation: | Department of Applied Physics and Chemistry, University of Electro-Communications, Chofu, Tokyo, 182-8585, Japan. |
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| Abstract: | One-dimensional polymeric complexes consisting of alternating dicopper(II) and digadolinium(III) units exhibited ferrimagnetic behavior which was ascribable to antiferromagnetic coupling across the oximate N-O bridges between the high-spin homodinuclear units. |
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