Facile in situ copper(II) mediated C-S bond activation transforming dithiocarbimate to carbamate and thiocarbamate generating Cu(II) and Cu(I) complexes |
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| Authors: | Diwan Kiran Singh Bandana Singh Santosh K Drew Michael G B Singh Nanhai |
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| Affiliation: | Department of Chemistry, Banaras Hindu University, Varanasi, UP 221005, India. |
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| Abstract: | Facile in situ Cu(II) mediated transformation of p-tolylsulfonyldithiocarbimate in conjunction with polypyridyl or phosphine ligands into corresponding carbamate and thiocarbamate led to the formation of new copper complexes with varying nuclearities and geometries, via C-S bond activation of the ligand within identical reaction systems. |
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