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Synthesis of Asymmetric Monomethine Cyanine Dyes with Red‐Shifted Optical Properties
Authors:Eduardo Soriano  Loretta Outler  Eric A Owens  Maged Henary
Institution:Department of Chemistry and Biochemistry, Georgia State University, Atlanta, Georgia, USA
Abstract:Six novel asymmetrical monomethine cyanine dyes were synthesized via the condensation reaction of 1‐butyl‐2‐(methylthio)benzoc,d]indol‐1‐ium iodide and various 1,5‐substituted indolenine salts under basic conditions. The dyes were characterized using UV–vis spectroscopy, fluorescence, 1H NMR, 13C NMR, and mass spectrometry; furthermore, the purity of these compounds was observed using LC/ELSD/MS.
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