A biomass carbon material with microtubule bundling and natural O-doping derived from goldenberry calyx and its electrochemical performance in supercapacitor |
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Authors: | Yang Liu Mengyi Zhang Liqiu Wang Yajuan Hou Chenxiao Guo Haiying Xin Shuang Xu |
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Affiliation: | College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao 066004, China; College of Pharmacy, State Key Laboratory of Medicinal Chemical Biology, Nankai University, Tianjin 300350, China; Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education), College of Chemistry, Nankai University, Tianjin 300071, China |
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Abstract: | A promising biomass carbon material, manufactured by the carbonation of Physalis peruviana L. calyx at 700℃, is presented in this work. Morphology characterization shows that the carbon material possesses long microtubule bundling and above 30% natural O-atom component on the surface. After KOH chemical etching, the materials maintain the oxygen content but exhibit more micropores and higher specific surface area up to 1732.6 m2/g. Using as an electrode material for supercapacitor, the active carbon material exhibits high specific capacitance up to 339.7 F/g at 0.5 A/g in 3 mol/L KOH aqueous solution through three-electrode system. The active carbon material also exhibits excellent cycling stability (97% retention) by 10,000 cycles at 10 A/g. The outstanding electrochemical performances are attributing to the unique long microtubule bundling with much more pores and the abundant O element on the surface. This biomass carbon material with excellent electrochemical properties could be a useful material for multiple applications. |
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Keywords: | Biomass carbon material Physalis peruviana L. calyx Carbon microtubule bundling High O-doping Supercapacitor |
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