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Metal-free visible-light-induced oxidative cyclization reaction of 1,6-enynes and arylsulfinic acids leading to sulfonylated benzofurans
Authors:Leilei Wang  Min Zhang  Yulong Zhang  Qishun Liu  Xiaohui Zhao  Jiang-Sheng Li  Zidan Luo  Wei Wei
Affiliation:School of Chemistry and Chemical Engineering;Qinghai Provincial Key Laboratory of Tibetan Medicine Research and Key Laboratory of Tibetan Medicine Research;School of Chemistry and food Engineering;School of Chemistry and Chemical Engineering
Abstract:A new and convenient visible-light-induced method has been developed for the synthesis of sulfonylated benzofurans via oxidative cyclization reaction of 1,6-enynes and arylsulfinic acids. This reaction was carried out under metal-free and mild conditions, in which the C-S, C-C and C=O bonds could be sequentially formed in one pot operation.
Keywords:Metal-free  Visible-light-catalysis  1  6-Enynes  Oxidative cyclization  Sulfonylated benzofurans  
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