On the optimal surfmer addition profile in emulsion polymerisation |
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| Authors: | Esteban Aramendia María J Barandiaran Jos M Asua |
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| Institution: | Institute for Polymer Materials (POLYMAT) and Grupo de Ingeniería Química, Departamento de Química Aplicada, Facultad de Ciencias Químicas, The University of the Basque Country, Apdo. 1072, ES-20080 Donostia-San, Sebastián, Spain |
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| Abstract: | In this work, the optimal surfmer feeding profile for stabilizing a high-solid-content acrylic latex with a non-ionic alkenyl functional TMMaxemul 5011 was calculated. For this purpose, the model developed by de la Cal and Asua (J. Polym. Sci., Part A: Polym. Chem. 39 (2001) 585) was used. It was observed that, in spite of the low reactivity of the surfmer, it was possible to increase substantially the surfmer conversion using an optimal surfmer addition policy. To cite this article: E. Aramendia et al., C. R. Chimie 6 (2003). |
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| Keywords: | surfmer emulsion polymerization optimal feeding profilesurfmè re polymé risation en é mulsion profil optimum d’ addition |
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