Reaction Between 5-Isopropylidene-2,2-dimethyl-1,3-dioxane-4,6-dione and <Emphasis Type="Italic">tert</Emphasis>-Butyl Isocyanide in the Presence of Primary or Secondary Amines |
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Authors: | Email author" target="_blank">Issa?YavariEmail author Azizollah?Habibi Mohammad R?Hosseini-Tabatabaei Hamid R?Bijanzadeh |
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Institution: | (1) Department of Chemistry, University of Tarbiat Modarres, Tehran, Iran, IR;(2) Department of Chemistry, Islamic Azad University, Zahedan, Iran, IR |
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Abstract: | Summary. 5-Isopropylidene-2,2-dimethyl-1,3-dioxane-4,6-dione (the condensation product of Meldrum s acid and acetone) reacts smoothly with tert-butyl isocyanide in the presence of primary or secondary amines to produce N-tert-butyl-2,2-dimethylbutyramide derivatives and/or 1-tert-butyl-4,4-dimethyl-2,5-dioxopyrrolidine-3-carboxamides in good yields. |
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Keywords: | s acid, Alkyl isocyanides, Triamides, Amidosuccinimides, Ugi reaction," target="_blank">,Meldrum s acid, Alkyl isocyanides, Triamides, Amidosuccinimides, Ugi reaction, |
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