Synthesis and characterization of novel grid coordination polymer networks generated from unsymmetrically bridging ligands |
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| Authors: | Shin Dong Mok Lee In Su Chung Young Keun Lah Myoung Soo |
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| Affiliation: | Department of Chemistry and the Center for Molecular Catalysis, College of Natural Sciences, Seoul National University, Seoul 151-742, Korea. |
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| Abstract: | Self-assembly between simple unsymmetrical ligands, such as 1-(3-pyridyl)-2-(4-pyridyl)ethene (L(1)) and 1-methyl-1'-(3-pyridyl)-2-(4-pyrimidyl)ethene (L(2)), and Co(NCS)(2) affords the unprecedented two-dimensional grid coordination polymers [Co(L(1))(2)(NCS)(2)](infinity) (1) and [Co(L(2))(2)(NCS)(2)](infinity) (2), respectively, with novel topological features which cannot be achieved using symmetrically bridging ligands. |
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