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The unusual paramagnetic mixed-metal carbonyl chalcogenide clusters: [E(2)Cr(2)Fe(CO)(10)](2-) (E = Te,Se)
Authors:Shieh Minghuey  Chung Ren-Ling  Yu Chun-Hsien  Hsu Miao-Hsing  Ho Chia-Hua  Peng Shie-Ming  Liu Yi-Hung
Institution:Departments of Chemistry, National Taiwan Normal University, Taipei, Taiwan, 116, Republic of China. mshieh@scc.ntnu.edu.tw
Abstract:The rare examples of electron-rich mixed-metal carbonyl telluride and selenide clusters E(2)Cr(2)Fe(CO)(10)](2-) (E = Te, Se) have been demonstrated. These two novel carbonyl complexes exhibit the unusual paramagnetic behavior.
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