| Synthesis and Crystal Structure of a Copper（Ⅱ） Complex with Benzilic Acid and 1,10-Phenanthroline |
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| 作者姓名： | XIE He-Ping, WANG Ying, LI Yu-Lin |
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| 作者单位： | [1]Department of Chemstry and Chemical Engineering, Hunan Institute of Technology, Hengyang 421002, China; [2]Department of Chemistry and Materials Science,Hengyang Normal University, Hengyang 421008, China |
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| 摘 要： | A new complex [Cu（phen）3][（C6H4）2C（OH）COO]2·6H2O was prepared by selfassembly of benzilic acid, 1,10-phenanthroline （phen）, and copper perchlorate. It crystallizes in triclinic, space group P1-, with a = 1.14661（17）, b = 1.6455（2）, c = 1.6457（2） nm, α= 74.779（2）, β = 74.904（3）, γ = 84.424（3）°, V = 2.8914（7） nm^3, Dc = 1.340 g/cm^3, Z = 2, F（000） = 1218, GOOF = 1.018, the final R = 0.0643 and wR= 0.1633. The crystal structure shows that the copper ion is coordinated with six nitrogen atoms from six 1,10-phenanthroline molecules, forming a distorted octahedral coordination geometry.
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| 关 键 词： | 铜(Ⅱ)配位化合物 晶体结构 合成 1,10-邻二氮杂菲 |
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