Palladium(II) octaalkylporphyrinates: Synthesis and spectral properties |
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Authors: | N V Chizhova O V Toldina N Zh Mamardashvili |
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Institution: | (1) Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheskaya 1, Ivanovo, 153045, Russia;(2) Ivanovo State University of Chemical Technology, pr. F. Engel’sa 7, Ivanovo, 153000, Russia |
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Abstract: | Palladium 3,7,13,17-tetramethyl-2,8,12,18-tetrabutylporphyrinate (I) and its 5,15-diaza (II), diphenyl (III), and di(4-bromophenyl) (IV) derivatives were synthesized by the complex formation reaction of palladium(II) chloride with corresponding tetrapyrrole ligands in dimethylformamide, and their spectral properties were studied. |
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