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Perovskite-type proton conductor for novel direct ionic thermoelectric hydrogen sensor
Authors:U. Rö  der-Roith,F. RettigK. Sahner,T. Rö  derJ. Janek,R. Moos
Affiliation:
  • a Functional Materials, University of Bayreuth, 95440 Bayreuth, Germany
  • b Institute of Physical Chemistry, Justus-Liebig-University Gießen, 35392 Gießen, Germany
  • Abstract:It was investigated whether a perovskite-type proton conductor, here BaCe0.95Y0.05O3  δ (BCY), is suitable as sensing material for a novel type of thermoelectric hydrogen sensor. Therefore, the hydrogen and oxygen concentration dependence of the thermopower of BaCe0.95Y0.05O3  δ was determined and was found to be in the same range as the value derived from theory. The hydrogen dependence was also measured at different temperatures, and only a comparatively small temperature dependence of the thermopower was observed.
    Keywords:Thermopower   Proton conductor   Solid electrolyte   Hydrogen   Sensor
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