| 镍硫配合物(Me3C+)2Ni(SCH2CH2S)2的合成及结构表征 |
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| 引用本文： | 刘云清,陈启元,曾志刚,张致贵.镍硫配合物(Me3C+)2Ni(SCH2CH2S)2的合成及结构表征[J].合成化学,2004,12(3):287-289. |
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| 作者姓名： | 刘云清 陈启元 曾志刚 张致贵 |
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| 作者单位： | 中南大学化学化工学院,湖南,长沙,410083;吉林大学化学学院,吉林,长春,130023 |
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| 摘 要： | 以NiCl2，Bu4NBr，HSCH2CH2SH为原料合成了配合物(Me3C^ )2Ni(SCH2CH2S)2，其结构经元素分析、IR，UV和^1H NMR确证，X-射线四圆衍射仪测其晶胞参数为：a=0.9127(1)nm，b=1．2424(0)nm，c=1．3906(2)，v=1．57685(2)nm^3，z=4，晶体属正交晶系。晶体结构经块状矩阵最小二乘法修正后，最终偏离因子R=0．089。
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| 关 键 词： | 配合物 [Me3C+]2Ni(SCH2CH2S)2 合成 晶体结构 |
| 文章编号： | 1005-1511(2004)03-0287-03 |
| 修稿时间： | 2003年9月29日 |
Synthesis and Characterization of Complex (Me3C+)2Ni(SCH2CH2S)2 |
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| LIU Yun-qing ,CHEN Qi-yuan,ZENG Zhi-gang ,ZHANG Zhi-gui.Synthesis and Characterization of Complex (Me3C+)2Ni(SCH2CH2S)2[J].Chinese Journal of Synthetic Chemistry,2004,12(3):287-289. |
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| Authors: | LIU Yun-qing CHEN Qi-yuan ZENG Zhi-gang ZHANG Zhi-gui |
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| Institution: | LIU Yun-qing 1,CHEN Qi-yuan,ZENG Zhi-gang 1,ZHANG Zhi-gui 2 |
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| Abstract: | A new complex (Me 3C +) 2Ni(SCH 2CH 2S) 2 was prepared from NiCl 2,Bu 4NBr and HSCH 2CH 2SH. The structure of the complex was characterized by elemental analysis, IR, UV and 1H NMR. Its crystal structure was determined by XRD. The parameters of the crystall cell for the complex are a=0.9127(1)nm, b=1.2424(0)nm, c=1.3906(2)nm, v=1.57685(2)nm 3 and Z=4. The final agreemeet factor is R=0.089 after the structure was refined by block-diagonal matrix least square method. |
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| Keywords: | complex (Me 3C +) 2Ni(SCH 2CH 2S) 2 synthesis crystal structure |
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