| 均相铬系催化剂的合成与催化α－烯烃聚合的进展 |
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| 引用本文： | 张浩,黄吉玲,钱延龙.均相铬系催化剂的合成与催化α－烯烃聚合的进展[J].有机化学,2002,22(12):981-989. |
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| 作者姓名： | 张浩 黄吉玲 钱延龙 |
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| 作者单位： | 华东理工大学金属有机化学研究室,上海,200237 |
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| 基金项目： | 国家重大基础 (No .G19990 6 480 1)研究项目，国家自然科学基金 (Nos .2 98710 10 ,2 0 0 72 0 0 4)资助项目 |
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| 摘 要： | 铬系多相催化剂已广泛应用于工业聚乙烯的生产中。近年来，探明多相铬催化 剂的本质，并进一步开发新一代铬系均相催化剂成为人们追求的热点。综述了近年 来有关均相铬催化剂的合成与催化α－烯烃的报道。
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| 关 键 词： | 铬 催化剂 烯烃 聚合 |
| 修稿时间： | 2001年11月27 |
Progress in Synthesis of Homogeneous Chromium Catalysts and Their Application in Olefin Polymerization |
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| ZHANG,Hao HUANG,Ji-Ling QIAN,Yan-Long.Progress in Synthesis of Homogeneous Chromium Catalysts and Their Application in Olefin Polymerization[J].Chinese Journal of Organic Chemistry,2002,22(12):981-989. |
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| Authors: | ZHANG Hao HUANG Ji-Ling QIAN Yan-Long |
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| Institution: | Laboratory of Organometallic Chemistry, East China University of Science and Technology.Shanghai(200237) |
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| Abstract: | Chromium-based heterogeneous catalysts are extensively used in industry in polymerization of olefins. In recent years, many investigations have been done on the active sites of chromium-based heterogeneous catalysts. Discovery of new generation chromium-based homogeneous catalysts has become a hot research area. This article summarizes the latest progresses in chromium-based homogeneous catalysts and their application in olefin polymerization. |
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| Keywords: | chromium complexes homogeneous catalysis olefin polymerization |
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