| 具有二重穿插结构的配位聚合物[Cu(bpy)(OH)]n的合成与结构表征 |
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| 引用本文： | 陈三平,范广,高胜利.具有二重穿插结构的配位聚合物[Cu(bpy)(OH)]n的合成与结构表征[J].化学学报,2007,65(14):1385-1388. |
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| 作者姓名： | 陈三平 范广 高胜利 |
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| 作者单位： | 西北大学化学系,陕西省物理无机化学重点实验室,西安,710069 |
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| 摘 要： | 利用水热反应, 合成了一个具有二重穿插结构的一价铜配位聚合物Cu(bpy)(OH)]n (1) (bpy＝4,4'-联吡啶), 并利用元素分析, X射线单晶衍射, 红外光谱以及热重分析等手段对标题化合物进行了表征. 晶体学数据: 四方晶系, I41/acd空间群, a＝1.41802(6) nm, b＝1.41802(6) nm, c＝3.8568(3) nm, β＝90.00°, V＝7.7552(7) nm3, Z＝32, S＝1.074, 最终残差因子I＞2σ(I)] R1＝0.0345, wR2＝0.0767, 对于全部数据R1＝0.0566, wR2＝0.0867.
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| 关 键 词： | 水热反应 二重穿插 配位聚合物 晶体结构 |
| 收稿时间： | 2006-12-7 |
| 修稿时间： | 2006-12-072007-03-25 |
Synthesis and Structural Characterization of a Two-Fold Penetration Coordination Polymer [Cu(bpy)(OH)]n |
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| CHEN San-Ping,FAN Guang,GAO Sheng-Li.Synthesis and Structural Characterization of a Two-Fold Penetration Coordination Polymer [Cu(bpy)(OH)]n[J].Acta Chimica Sinica,2007,65(14):1385-1388. |
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| Authors: | CHEN San-Ping FAN Guang GAO Sheng-Li |
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| Institution: | (Department of Chemistry, Shaanxi Key Laboratory of Physico-inorganic Chemistry, Northwest University, Xi'an 710069) |
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| Abstract: | A two-fold penetration coordination polymer Cu(bpy)(OH)]n (1) (bpy＝4,4'-bipyridyl) has been synthesized through hydrothermal reaction and structurally characterized by single crystal X-ray diffraction method. Crystal data: tetragonal, space group I41/acd, a＝1.41802(6) nm, b＝1.41802(6) nm, c＝3.8568(3) nm, β＝90.00°, V＝7.7552(7) nm3, Z＝32, S＝1.074, final R indices I＞2σ(I)] R1＝0.0345, wR2＝0.0767, for all reflections R1＝0.0566, wR2＝0.0867. In addition, the results of elemental analysis, IR and thermogravimetric analysis were presented. |
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| Keywords: | hydrothermal reaction two-fold penetration coordination polymer crystal structure |
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