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Spiroketals via oxidative rearrangement of enol ethers |
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| Authors: | Waller David L Stephenson Corey R J Wipf Peter |
| Institution: | Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania, USA. |
| Abstract: | Oxidative rearrangement of cyclic enol ethers leads to alpha-alkoxyesters. In the presence of a neighboring spiroether, this approach provides a stereoselective access to spiroketals. A modified proposal for the biosynthesis of acutumine is presented. |
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