一个新的钴磷酸盐配合物Co(μ3-O3P)·H2O的合成与晶体结构 |
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作者姓名: | 杜晨霞 薛东旭 程小宁 樊耀亭 侯红卫 卢会杰 |
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作者单位: | 郑州大学化学系,郑州 450052,郑州大学化学系,郑州 450052,郑州大学化学系,郑州 450052,郑州大学化学系,郑州 450052,郑州大学化学系,郑州 450052,郑州大学化学系,郑州 450052 |
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基金项目: | 国家自然科学基金资助项目(No.20171040)。 |
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摘 要: | A new layered cobalt phosphate complex, Co( μ3-O3P)·H2O, was prepared by the hydrothermal reaction. The crystal structure of the complex was determined by single-crystal X-ray diffraction. The results indicate that it contains two different infinite PO3chains linked by CoO6 octahedra with infinite 1-D tunnels. It crystallizes in the orthorhombic space group Pbcm with a=0.790 12(16) nm, b=0.900 25(18) nm, c=1.016 1(2) nm, β=90°, V=1.245 3nm3, Z=4. Refinement gave R1=0.068 5, wR2=0.175 1 for 2 133 unique observed reflections (I>2σ(I)). The title complex was also characterized by IR, TG-DTA and chemical analysis. CSD: 413934.
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关 键 词: | 钴磷酸盐 配合物 晶体结构 |
修稿时间: | 2004-02-02 |
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