| 气液色谱法研究Ni[(C8H17)O)2PS2]2与脂肪胺加合反应的热力学性质 |
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| 引用本文： | 徐正,俞运鹏,游效曾. 气液色谱法研究Ni[(C8H17)O)2PS2]2与脂肪胺加合反应的热力学性质[J]. 物理化学学报, 1988, 4(1): 88-91. DOI: 10.3866/PKU.WHXB19880118 |
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| 作者姓名： | 徐正 俞运鹏 游效曾 |
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| 作者单位： | Coordination Chemistry Institute; Nanjing University |
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| 摘 要： |
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| 收稿时间： | 1986-10-09 |
| 修稿时间： | 1987-04-04 |
THE STUDY ON THERMODYNAMIC PROPERTIES OF ADDUCT REACTIONS OF BIS-(O,O'-DIOCTYLDITHIOPHOSPHATO) NICKEL (Ⅱ) WITH ALKYLAMINE BY GLC METHOD |
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| Xu Zheng,Yu Yunpeng,You Xiaozeng. THE STUDY ON THERMODYNAMIC PROPERTIES OF ADDUCT REACTIONS OF BIS-(O,O'-DIOCTYLDITHIOPHOSPHATO) NICKEL (Ⅱ) WITH ALKYLAMINE BY GLC METHOD[J]. Acta Physico-Chimica Sinica, 1988, 4(1): 88-91. DOI: 10.3866/PKU.WHXB19880118 |
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| Authors: | Xu Zheng Yu Yunpeng You Xiaozeng |
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| Affiliation: | Coordination Chemistry Institute; Nanjing University |
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| Abstract: | The equilibium constants of acid-base interaction between Mi(Octyl_dtp)_2 and alkylamine were determined by GLC method at several temperatures. Thermodynamic parameters △H and △S were evaluted as follows:ethylamine: △H=-11.5kJ mol~(-1) △S=-22.7J K~(-1) mol~(-1)diethylamine: △H=-18.1kJ mol~(-1) △S=-42.1J K~(-1) mol~(-1)The variations of logK versus temperature fit following equations:ethylamine: lgK=-1.19+598.9/Tdiethylamine: lgK=-2.20+945.6/T |
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