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Rapid aerobic iodination of arenes mediated by hypervalent iodine in fluorinated solvents |
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| Authors: | Jernej Iskra S. Shaun Murphree |
| Affiliation: | 1. Laboratory for Organic and Bioorganic Chemistry, “Jo?ef Stefan” Institute, Jamova 39, 1000 Ljubljana, Slovenia;2. Faculty of Chemistry and Chemical Technology, University of Ljubljana, Ve?na pot 113, 1000 Ljubljana, Slovenia;3. Department of Chemistry, Allegheny College, 520 North Main Street, Meadville, PA, USA |
| Abstract: | Arenes are rapidly converted to the corresponding iodides by aerobic oxidative iodination at room temperature by treatment with iodine and catalytic quantities of nitrous acid in a fluorinated solvent. Dichloroiodic acid is proposed as the actual iodination reagent. |
| Keywords: | Aromatic substitution Hypervalent compounds Iodination Fluorinated solvents |
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