Reaction of Perfluoro-1-methylbenzocyclobutene with Pentafluorobenzene in SbF5 Medium |
| |
Authors: | Sinyakov V. R. Mezhenkova T. V. Karpov V. M. Platonov V. E. Rybalova T. V. Gatilov Yu. V. |
| |
Affiliation: | (1) Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630090, Russia |
| |
Abstract: | A reaction of perfluoro-1-methylbenzocyclobutene with pentafluorobenzene in SbF5 medium followed by treating the reaction mixture with water gave rise to perfluoro-1-methyl-1-phenylbenzocyclobutene, perfluoro-1-methyl-2-phenylbenzocyclobutene, 2-hydroxyperfluoro-1-methyl-2-phenylbenzocyclobutene, and also to small amounts of 1-(2-trifluoromethyltetrafluorophenyl)-1-pentafluorophenyl-2,2,2-trifluoroethane, and perfluoro-1-(2-methylphenyl)-1-phenylethylene. In a crystal of (E)-2-hydroxyperfluoro-1-methyl-2-phenylbenzocyclobutene for a dimer molecular pair a -stacking interaction between pentafluorophenyl groups was found. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|