| 不锈钢表面修饰纳米合金膜电极的电催化活性研究 |
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| 引用本文： | 万新军,褚道葆,陈声培,黄桃,侯晓雯,孙世刚.不锈钢表面修饰纳米合金膜电极的电催化活性研究[J].安徽师范大学学报(自然科学版),2007,30(5):567-569. |
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| 作者姓名： | 万新军 褚道葆 陈声培 黄桃 侯晓雯 孙世刚 |
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| 作者单位： | 安徽师范大学化学与材料科学学院,芜湖,241000;巢湖学院化学系,安徽,巢湖,238000;安徽师范大学化学与材料科学学院,芜湖,241000;厦门大学化学系,福建,厦门,361005 |
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| 基金项目： | 安徽省教育厅自然科学基金 |
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| 摘 要： | 以不锈钢(SS)作基底,自行研制不锈钢载纳米表面合金电催化材料(Surface alloy/SS),并运用循环伏安法(CV)和扫描电镜(SEM)等技术对该催化剂进行结构和性能表征.SEM研究表明,所研制的Surface alloy/SS电催化剂是一种由粒度主要约为100nm的颗粒合金组成的薄膜.循环伏安研究表明,所研制的Surface alloy/SS电催化剂在常温常压下对顺丁烯二酸的加氢还原表现出很高的电催化活性.顺丁烯二酸的起始还原电位为-0.4V,与通常用的阴极铅材料相比,正移约200mV.
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| 关 键 词： | 不锈钢载表面合金 电催化还原 循环伏安 SEM 顺丁烯二酸 |
| 文章编号： | 1001-2443（2007）05-0567-03 |
| 收稿时间： | 2006-12-20 |
Electrocatalytic Activities of the Film Electrode Modified Nanocrystalline Alloy on the Stainless Steel |
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| WAN Xin-jun,CHU Dao-bao,CHEN Sheng-pei,HUANG Tao,HOU Xiao-wen,SUN Shi-gang.Electrocatalytic Activities of the Film Electrode Modified Nanocrystalline Alloy on the Stainless Steel[J].Journal of Anhui Normal University(Natural Science Edition),2007,30(5):567-569. |
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| Authors: | WAN Xin-jun CHU Dao-bao CHEN Sheng-pei HUANG Tao HOU Xiao-wen SUN Shi-gang |
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| Institution: | 1. College of Chemistry and Material Science, Anhui Normal University, Wuhu 241000, China ;2. Department of Chemistry, Chaohu College, Chaohu 238000, China;3. Department of Chemistry, Xiamen University, Xiamen 361005, China |
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| Abstract: | Electro-catalysts of surface alloy supported on the stainless steel were prepared.Structures and properties of these electro-catalysts were studied through techniques of cyclic voltammetry(CV) and scanning electron microscope(SEM).The results of characterization by SEM have converged to illustrate that the surface alloy film is composed of nano-particles of about 100 nanometers in regular distribution.Cyclic voltammetry research indicated that Surface alloy/SS displays the very high electricity catalytic activity to the cis-butenedioic acid hydrogenation reduction under the normal temperature and atmospheric pressure.The over potential of cis-butenedioic acid was significantly reduced by about 200mV in comparison with that measured on a Pb cathode that was used industrially for the reduction. |
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| Keywords: | surface alloy supported the stainless steel electricity catalysis reduction cyclic voltammetry SEM cis-butenedioic acid |
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