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Synthesis of mono- and disubstituted tetra(tert-butyl)porphyrazines
Authors:E. A. Makarova  V. N. Kopranenkov  V. K. Shevtsov  E. A. Luk'yanets
Abstract:Bromination of tetra(tert-butyl)porphyrazine by N-bromosuccinimide in chloroform results in the formation of mono- and dibromides, substitution for the bromine atoms of which produced the corresponding cyano, phenoxy, phenylthio, styryl, phenylethynyl and piperidino derivatives. From the monobromide and 2,2-bis(p-hydroxyphenyl)propane, the dimeric porphyrazine 2,2-bis[p-tetra(tert-butyl)porphyrazyloxyphenyl]propane was similarly obtained.Scientific Research Institute of Organic Intermediate Products and Dyes, Moscow 103787. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1206–1212, September, 1994. Original article submitted September 6, 1994.
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