Potentiometric determination of some common alkaloids with a picrate-selective electrode |
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Authors: | E.P. Diamandis T.P. Hadjiioannou |
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Affiliation: | Laboratory of Analytical Chemistry, University of Athens, AthensGreece |
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Abstract: | Potentiometric methods are described for the determination of alkaloids, based on the formation of insoluble alkaloid picrate salts, using a picrate ion-selective indicating electrode. Micro-amounts of strychnine, papaverine, quinine and cocaine were determined by direct potentiometry and titrimetrically, using Gran plots, with average errors of about 4% and 2%, respectively. The method was successfully applied to pharmaceutical preparations. |
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