Chloride interference with non-stoichiometric copper sulphide coppers-selective electrodes : Part 1. Mechanisms |
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| Authors: | Tadeusz Hepel |
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| Institution: | Institute of Chemistry, Jagiellonian University, 30-060 KrakówPoland |
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| Abstract: | The behaviour of copper(II)-selective electrodes made of non-stoichiometric copper sulphide single crystals is discussed. The mechanism of chloride ion interference with the electrode operation is considered on the basis of potentiometric and dynamic measurements. The occurrence of irreversible processes at the electrode surface is described. |
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