Extension of the Theory of Volume Filling of Micropores to Adsorption in Supermicropores |
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| Authors: | N S Polyakov G A Petukhova |
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| Institution: | (1) Institute of Physical Chemistry, Russian Academy of Sciences, 31 Leninsky Prosp., 119991 Moscow, Russian Federation |
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| Abstract: | An enhancement in characteristic energy of adsorption in large micropores is analyzed. The effect is due to the overlapping
of potential fields from opposite walls of pores and to reduction of the surface adsorption film on filling the micropore
volume. The effects of both factors are comparable in magnitude and dependent on the micropore size.
This work is devoted to memory of the professor W. Schirmer |
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| Keywords: | non-porous and supermicroporous adsorbents characteristic energy of adsorption adsorption potential polymolecular adsorption |
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