Spectroscopic constants of the known electronic states of lead monofluoride

Based on measurements made by mass-resolved 1 + 1′ + 1″ resonance-enhanced multiphoton ionization spectroscopy, we have determined new molecular constants describing the rotational and fine structure levels of the B, D, E, and F states of the most abundant isotopic variant ²⁰⁸Pb¹⁹F, and we summarize the spectroscopic constants for all the know electronic states of the radical. Many spectroscopic constants for the isotopologues ²⁰⁶Pb¹⁹F and ²⁰⁷Pb¹⁹F have also been determined. The symmetry of the D-state is found to be ²Π_1/2, and the F-state is found to be an Ω = 3/2 state.