| 两种季铵盐型离子液体钯配合物的合成 |
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| 引用本文： | 籍向东,王宇,蔡亮亮,高建疆. 两种季铵盐型离子液体钯配合物的合成[J]. 合成化学, 2020, 28(3): 234-238. DOI: 10.15952/j.cnki.cjsc.1005-1511.18306 |
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| 作者姓名： | 籍向东 王宇 蔡亮亮 高建疆 |
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| 作者单位： | 河西学院 甘肃省河西走廊特色资源利用重点实验室，甘肃 张掖 734000 |
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| 基金项目： | 河西学院第八批大学生科技创新项目;甘肃省科技计划资助项目 |
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| 摘 要： | 以苯甲酰肼和4-醛基吡啶为原料，经过缩合反应制备亚胺型化合物1，分别与苄氯和对二苄氯结合制备了两个新型的离子液体型亚胺配体2和3，配体2和3分别与醋酸钯反应得到新型离子液体型钯配合物4和离子液体型自组装钯配合物5，其结构经1H NMR，13C NMR，IR和MS确证。
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| 关 键 词： | 苯甲酰肼 吡啶 离子液体 钯配合物 缩合反应 合成 |
Synthesis of Two Ionic Liquid Palladium Complexes with Quaternary Ammonium Salt |
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| JI Xiang-dong,WANG Yu,CAI Liang-liang,GAO Jian-jiang. Synthesis of Two Ionic Liquid Palladium Complexes with Quaternary Ammonium Salt[J]. Chinese Journal of Synthetic Chemistry, 2020, 28(3): 234-238. DOI: 10.15952/j.cnki.cjsc.1005-1511.18306 |
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| Authors: | JI Xiang-dong WANG Yu CAI Liang-liang GAO Jian-jiang |
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| Affiliation: | Key Laboratory of Hexi Corridor Resources Utilization of Gansu, Hexi College, Zhangye 734000, China |
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| Abstract: | A novel imine compound 1 was synthesized by condensation reaction using benzoyl hydrazine and 4-pyridinecarboxaldehyde as the starting material.The ionic liquid type of imine compounds 2 and 3 were obtained by reaction of compound 1 with benzyl chloride and 1,4-bis(chloromethyl)benzene,respectively.The ionic liquid type of palladium complex 4 and self-assembled palladium complex 5 were synthesized by reaction of Pd(OAc)2 to compound 2 and 3,respectively.The structures were confirmed by 1H NMR,13C NMR,IR and HR-MS(ESI). |
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| Keywords: | benzoyl hydrazine pyridne ionic liquid palladium complexe condensation synthesis |
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